3-methyl-1-[3-(3-methyl-2-oxobutylidene)-1,4-dihydro-6-methyl-quinoxalin-2-ylidene]butan-2-one.

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4-Hy­droxy-3-[(4-hy­droxy-6-methyl-2-oxo-3,6-dihydro-2H-pyran-3-yl)(3-thien­yl)meth­yl]-6-methyl-3,6-dihydro-2H-pyran-2-one

The asymmetric unit of the title compound, C(17)H(14)O(6)S, contains four crystallographically independent mol-ecules in which the pyran-one units are essentially planar, with maximum deviations of 0.016 (2), 0.019 (2), 0.025 (2), 0.014 (2), 0.020 (2), 0.010 (2), 0.003 (2) and 0.012 (2) Å. One of the thio-phene rings is disordered over two positions, with an occupancy ratio of 0.739 (4):0.261 (...

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(E)-3-(2-Chloro-6-methyl-3-quinol­yl)-1-(2,3-dihydro-1,4-benzodioxin-6-yl)prop-2-en-1-one

In the title mol-ecule, C(21)H(16)ClNO(3), the quinoline and benzene rings are inclined at 56.96 (6)° with respect to each other and the dioxine ring is in a twist-chair conformation. The structure is devoid of any classical hydrogen bonds. Rather weak inter-molecular hydrogen-bonding inter-actions of the types C-H⋯N and C-H⋯O are present, consolidating the crystal structure.

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1-Methyl-3-phenyl­quinoxalin-2(1H)-one

The phenyl substituents in both independent mol-ecules of the title compound, C(15)H(12)N(2)O, are twisted with respect to the quinoxaline system [dihedral angles = 19.3 (1) and 30.4 (1)°].

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3-Methyl-1-propargylquinoxalin-2(1H)-one

The ten-membered fused ring of the title compound, C(12)H(10)N(2)O, is essentially planar in the two independent mol-ecules of the asymmetric unit (r.m.s. deviations = 0.012 and 0.015 Å).

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3-Methyl-1-(prop-2-en-1-yl)quinoxalin-2(1H)-one

In the mol-ecule of the title compound, C(12)H(12)N(2)O, the quinoxaline ring is planar with an r.m.s. deviation of 0.007 (15) Å. The dihedral angle between the quinoxaline and propenyl planes is 82.1 (2)°. The crystal packing is stabilized by offset π-π stacking between the quinoxaline rings [centroid-centroid distance = 3.8832 (9) Å].

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ژورنال

عنوان ژورنال: Molbank

سال: 2004

ISSN: 1422-8599

DOI: 10.3390/m384